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Mercaptans, sulphides and sulphones

Robinson Brothers Ltd has developed novel processing chemistry to produce a range of long chain mercaptans with a characteristic low odour property. This enables our mercaptans, such as octadecyl mercaptan (ODM) and hexadecyl mercaptan (HDM), to be used in a broad range of applications. Thus, ODM and HDM are used as chain transfer agents to control polymer growth; as modifiers in polysulphide resins and as anti-tarnishing agents in silver polish. HDM, 11-mercaptoundecanoic acid and eicosanethiol (ECT) are also used within monolayer lithography applications.

RBL has recently developed a broad range of long chain branched thiols, such as dipentaerythritol hexakis thiogycollate, for use as multi-functional cross linking agents in resin, adhesives and coatings production. Also for the electronic and coatings market, RBL is able to offer t-butyl thiophenol.

From sulphur coupling and oxidation, RBL is able to offer a range of sulphides and sulphones. Examples include the pharmaceutical intermediate, cystamine dihydrochloride and photographic intermediates such as tetramethyl cystamine hydrochloride and tribromophenylmethylsulphone.

 Product  Status
 Octadecyl mercaptan (ODM)  commercial
 Hexadecyl mercaptan (HDM)  commercial 
 Eicosanethiol (ECT)  special purchase
 2-Ethyl-1-hexane thiol  development
 11-mercaptoundecanoic acid  commercial
 Dipenta erythritol hexakis thioglycollate (DPHTG)  development 
 Penta erythritol tetrakis-[3-mercaptopropionoate] (PP150-TMP) 

 development

 4-tert-Butylthiophenol  development 
 cystamine dihydrochloride  special purchase
 N,N,N',N'-Tetramethylcystamine dihydrochloride (TMC HCl)  commercial
 Tribromomethyl phenyl sulfone (TBMPS)  commercial
 3-mercaptobenzoic acid  development